Cover Picture: Reagents with a Crystalline Coat (Angew. Chem. Int. Ed. 44/2016) | Zendy

Schwenger Alexander | Zendy; Frey Wolfgang | Zendy; Richert Clemens | Zendy

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Cover Picture: Reagents with a Crystalline Coat (Angew. Chem. Int. Ed. 44/2016)

Author(s) -

Schwenger Alexander,

Frey Wolfgang,

Richert Clemens

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201609250

Subject(s) - reagent , benzoyl chloride , isocyanide , chemistry , adamantane , solvent , chloride , reactivity (psychology) , polymer chemistry , combinatorial chemistry , organic chemistry , medicine , alternative medicine , pathology

The encapsulation of aggressive reagents in organic crystals facilitates their handling while their reactivity is restored upon release in a suitable solvent. In their Communication on page 13706 ff., C. Richert et al. show that noxious reagents, such as benzoyl chloride, PCl 3 , and cyclohexyl isocyanide, can be encapsulated in tetrakis(dimethoxyphenyl)adamantane crystals. The cover picture depicts a forest, through which hazardous reagents may now be transported more safely, as well as the release of benzoyl chloride from the inclusion complex upon demand. Graphic credit: Matthäus Kalinowski and Alexander Schwenger.

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