Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex | Zendy

Guo JingJing | Zendy; Hu Anhua | Zendy; Chen Yilin | Zendy; Sun Jianfeng | Zendy; Tang Haoming | Zendy; Zuo Zhiwei | Zendy

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Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex

Author(s) -

Guo JingJing,

Hu Anhua,

Chen Yilin,

Sun Jianfeng,

Tang Haoming,

Zuo Zhiwei

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201609035

Subject(s) - amination , chemistry , cerium , bond cleavage , catalysis , cleavage (geology) , photocatalysis , surface modification , photochemistry , chloride , organic chemistry , polymer chemistry , combinatorial chemistry , materials science , fracture (geology) , composite material

A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible‐light‐induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols.

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