Back Cover: Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross‐Coupling of Primary Aryl Amines with Aryl Halides (Angew. Chem. Int. Ed. 42/2016) | Zendy

Oderinde Martins S. | Zendy; Jones Natalie H. | Zendy; Juneau Antoine | Zendy; Frenette Mathieu | Zendy; Aquila Brian | Zendy; Tentarelli Sharon | Zendy; Robbins Daniel W. | Zendy; Johannes Jeffrey W. | Zendy

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Back Cover: Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross‐Coupling of Primary Aryl Amines with Aryl Halides (Angew. Chem. Int. Ed. 42/2016)

Author(s) -

Oderinde Martins S.,

Jones Natalie H.,

Juneau Antoine,

Frenette Mathieu,

Aquila Brian,

Tentarelli Sharon,

Robbins Daniel W.,

Johannes Jeffrey W.

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201607767

Subject(s) - iridium , amination , aryl , catalysis , nickel , photoredox catalysis , halide , chemistry , photochemistry , coupling (piping) , combinatorial chemistry , materials science , photocatalysis , organic chemistry , alkyl , metallurgy

The cogs of Ir photoredox and Ni catalysts have been merged to provide a new and powerful approach to cross‐coupling. As described by M. S. Oderinde, J W. Johannes et al. in their Communication on page 13219 ff., aryl amination was achieved by employing an Ir photoredox/Ni dual‐catalytic platform with inexpensive blue LED irradiation. The dual ability of the Ir complex to oxidize arylamines and reduce Ni II by an outer‐sphere single‐electron‐transfer process enabled C−N cross‐coupling under remarkably mild conditions.

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