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Polystyrene Sulfonate Threaded through a Metal–Organic Framework Membrane for Fast and Selective Lithium‐Ion Separation
Author(s) -
Guo Yi,
Ying Yulong,
Mao Yiyin,
Peng Xinsheng,
Chen Banglin
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201607329
Subject(s) - sulfonate , membrane , lithium (medication) , salt (chemistry) , chemistry , extraction (chemistry) , polystyrene sulfonate , inorganic chemistry , ion , conductivity , metal , chemical engineering , sodium , chromatography , organic chemistry , electrode , medicine , biochemistry , pedot:pss , engineering , endocrinology
Extraction of lithium ions from salt‐lake brines is very important to produce lithium compounds. Herein, we report a new approach to construct polystyrene sulfonate (PSS) threaded HKUST‐1 metal–organic framework (MOF) membranes through an in situ confinement conversion process. The resulting membrane PSS@HKUST‐1‐6.7, with unique anchored three‐dimensional sulfonate networks, shows a very high Li + conductivity of 5.53×10 −4 S cm −1 at 25 °C, 1.89×10 −3 S cm −1 at 70 °C, and Li + flux of 6.75 mol m −2 h −1 , which are five orders higher than that of the pristine HKUST‐1 membrane. Attributed to the different size sieving effects and the affinity differences of the Li + , Na + , K + , and Mg 2+ ions to the sulfonate groups, the PSS@HKUST‐1‐6.7 membrane exhibits ideal selectivities of 78, 99, and 10296 for Li + /Na + , Li + /K + , Li + /Mg 2+ and real binary ion selectivities of 35, 67, and 1815, respectively, the highest ever reported among ionic conductors and Li + extraction membranes.