Copper‐Catalyzed Oxidation of Alkanes with H 2 O 2  under a Fenton‐like Regime | Zendy

GarciaBosch Isaac | Zendy; Siegler Maxime A. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Copper‐Catalyzed Oxidation of Alkanes with H 2 O 2 under a Fenton‐like Regime

Author(s) -

GarciaBosch Isaac,

Siegler Maxime A.

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201607216

Subject(s) - catalysis , copper , chemistry , inorganic chemistry , materials science , chemical engineering , metallurgy , organic chemistry , engineering

Copper complexes bearing readily available ligand systems catalyzed the oxidation of alkanes with H 2 O 2 as the oxidant with high efficiency in remarkable yields (50–60 %). The reactions proceeded with unprecedented selectivity to give alkyl hydroperoxides as the major products. Detailed scrutiny of the reaction mechanism suggests the involvement of C‐centered and O‐centered radicals generated in a Fenton‐like fashion.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research