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A Kinetic Self‐Sorting Approach to Heterocircuit [3]Rotaxanes
Author(s) -
Neal Edward A.,
Goldup Stephen M.
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201606640
Subject(s) - sorting , rotaxane , product (mathematics) , process (computing) , kinetic energy , yield (engineering) , coupling (piping) , nanotechnology , biological system , computer science , chemistry , materials science , supramolecular chemistry , mathematics , algorithm , physics , molecule , biology , geometry , classical mechanics , organic chemistry , metallurgy , operating system
In this proof‐of‐concept study, an active‐template coupling is used to demonstrate a novel kinetic self‐sorting process. This process iteratively increases the yield of the target heterocircuit [3]rotaxane product at the expense of other threaded species.