Cover Picture: Porous Molybdenum Phosphide Nano‐Octahedrons Derived from Confined Phosphorization in UIO‐66 for Efficient Hydrogen Evolution (Angew. Chem. Int. Ed. 41/2016) | Zendy

Yang Jian | Zendy; Zhang Fengjun | Zendy; Wang Xin | Zendy; He Dongsheng | Zendy; Wu Geng | Zendy; Yang Qinghua | Zendy; Hong Xun | Zendy; Wu Yuen | Zendy; Li Yadong | Zendy

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Cover Picture: Porous Molybdenum Phosphide Nano‐Octahedrons Derived from Confined Phosphorization in UIO‐66 for Efficient Hydrogen Evolution (Angew. Chem. Int. Ed. 41/2016)

Author(s) -

Yang Jian,

Zhang Fengjun,

Wang Xin,

He Dongsheng,

Wu Geng,

Yang Qinghua,

Hong Xun,

Wu Yuen,

Li Yadong

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201606586

Subject(s) - materials science , phosphide , molybdenum , nanoparticle , metal organic framework , porosity , chemical engineering , nano , nanotechnology , hydrogen , carbon fibers , metal , metallurgy , chemistry , composite material , adsorption , organic chemistry , engineering , composite number

The Confinement Effect of metal–organic frameworks (MOFs) allows MoO 2 nanoparticles@porous carbon to be fabricated by subliming MoO 3 into the pores of the MOF UIO‐66. The resulting MoO 2 nanpoarticles (NPs) were converted into MoP at 850 °C by PH 3 which was generated in situ. In their Communication on page 12854 ff. Y. Wu, Y. Li, and co‐workers show that using this strategy, MoP NPs confined in porous carbon are obtained and exhibit higher hydrogen evolution reaction (HER) activity than bulk MoP.

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