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Nickel Catalysis Enables Oxidative C(sp 2 )–H/C(sp 2 )–H Cross‐Coupling Reactions between Two Heteroarenes
Author(s) -
Cheng Yangyang,
Wu Yimin,
Tan Guangyin,
You Jingsong
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201606529
Subject(s) - nickel , catalysis , coupling reaction , scope (computer science) , oxidative coupling of methane , chemistry , substrate (aquarium) , oxidative phosphorylation , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry , computer science , biochemistry , biology , programming language , ecology
Nickel can be used to promote oxidative C(sp 2 )−H/C(sp 2 )−H cross‐coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional‐group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.