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Bis(4‐nitraminofurazanyl‐3‐azoxy)azofurazan and Derivatives: 1,2,5‐Oxadiazole Structures and High‐Performance Energetic Materials
Author(s) -
Liu Yuji,
Zhang Jiaheng,
Wang Kangcai,
Li Jinshan,
Zhang Qinghua,
Shreeve Jean'ne M.
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201606378
Subject(s) - azoxy , detonation velocity , detonation , energetic material , explosive material , bond dissociation energy , materials science , dissociation (chemistry) , chemistry , enthalpy , high pressure , computational chemistry , thermodynamics , organic chemistry , physics
Bis(4‐nitraminofurazanyl‐3‐azoxy)azofurazan ( 1 ) and ten of its energetic salts were prepared and fully characterized. Computational analysis based on isochemical shielding surface and trigger bond dissociation enthalpy provide a better understanding of the thermal stabilities for nitramine‐furazans. These energetic compounds exhibit good densities, high heats of formation, and excellent detonation velocity and pressure. Some representative compounds, for example, 1 ( v D : 9541 m s −1 ; P : 40.5 GPa), and 4 ( v D : 9256 m s −1 ; P : 38.0 GPa) exhibit excellent detonation performances, which are comparable with current high explosives such as RDX ( v D : 8724 m s −1 ; P : 35.2 GPa) and HMX ( v D : 9059 m s −1 ; P : 39.2 GPa).