Premium
Hydrothermal Synthesis of Metal–Polyphenol Coordination Crystals and Their Derived Metal/N‐doped Carbon Composites for Oxygen Electrocatalysis
Author(s) -
Wei Jing,
Liang Yan,
Hu Yaoxin,
Kong Biao,
Zhang Jin,
Gu Qinfen,
Tong Yuping,
Wang Xianbiao,
Jiang San Ping,
Wang Huanting
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201606327
Subject(s) - electrocatalyst , catalysis , metal , cobalt , materials science , polymerization , polyphenol , hydrothermal synthesis , metal organic framework , hydrothermal circulation , chemical engineering , oxygen evolution , metal ions in aqueous solution , carbon fibers , oxygen , inorganic chemistry , chemistry , polymer , composite material , organic chemistry , composite number , metallurgy , electrochemistry , electrode , adsorption , antioxidant , engineering
Cobalt (or iron)–polyphenol coordination polymers with crystalline frameworks are synthesized for the first time. The crystalline framework is formed by the assembly of metal ions and polyphenol followed by oxidative self‐polymerization of the organic ligands (polyphenol) during hydrothermal treatment in alkaline condition. As a result, such coordination crystals are even partly stable in strong acid (such as 2 m HCl). The metal (Co or Fe)‐natural abundant polyphenol (tannin) coordination crystals are a renewable source for the fabrication of metal/carbon composites as a nonprecious‐metal catalyst, which show high catalytic performance for both oxygen reduction reaction and oxygen evolution reaction. Such excellent performance makes metal–polyphenol coordination crystals an efficient precursor to fabricate low‐cost catalysts for the large‐scale application of fuel cells and metal–air batteries.