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J (Si,H) Coupling Constants in Nonclassical Transition‐Metal Silane Complexes
Author(s) -
Scherer Wolfgang,
Meixner Petra,
Batke Kilian,
BarqueraLozada José E.,
Ruhland Klaus,
Fischer Andreas,
Eickerling Georg,
Eichele Klaus
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201604001
Subject(s) - silane , sign (mathematics) , coupling (piping) , transition metal , coupling constant , chemistry , salient , measure (data warehouse) , metal , chemical physics , computational chemistry , materials science , physics , quantum mechanics , organic chemistry , computer science , mathematics , metallurgy , catalysis , mathematical analysis , database , artificial intelligence
We will outline that the sign and magnitude of J (Si,H) coupling constants provide a highly sensitive tool to measure the extent of Si−H bond activation in nonclassical silane complexes. Up to now, this structure–property relationship was obscured by erroneous J (Si,H) sign determinations in the literature. These new findings also help to identify the salient control parameters of the Si−H bond activation process in nonclassical silane complexes.