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Coupling of Carbon Monoxide with Nitrogen Monoxide at a Frustrated Lewis Pair Template
Author(s) -
Ye KeYin,
Kehr Gerald,
Daniliuc Constantin G.,
Liu Lei,
Grimme Stefan,
Erker Gerhard
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201603760
Subject(s) - carbon monoxide , chemistry , coupling (piping) , nitrogen , lewis acids and bases , monoxide , frustrated lewis pair , carbon monoxide dehydrogenase , hydrogen , photochemistry , catalysis , inorganic chemistry , organic chemistry , materials science , metallurgy
Abstract Coupling of carbon monoxide with nitrogen monoxide was achieved at a frustrated Lewis pair template. This unique reaction uses hydride as an auxiliary, which reductively activates carbon monoxide at the frustrated Lewis pair. The CO/NO coupling reaction then takes place through a pathway involving a radical reaction in which the hydrogen atom auxiliary is eventually removed again.