Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC) 2  Tectons Driven by Metallophilic Interactions | Zendy

Ruiz Javier | Zendy; García Lucía | Zendy; Sol Daniel | Zendy; Vivanco Marilín | Zendy

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Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC) 2 Tectons Driven by Metallophilic Interactions

Author(s) -

Ruiz Javier,

García Lucía,

Sol Daniel,

Vivanco Marilín

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201603688

Subject(s) - metalation , self assembly , crystallography , chemistry , stereochemistry , nanotechnology , materials science

A new protocol for the synthesis of protic bis(N‐heterocyclic carbene) complexes of Au I by a stepwise metal‐controlled coupling of isocyanide and propargylamine is described. They are used as tectons for the construction of supramolecular architectures through metalation and self‐assembly. Notably a unique polymeric chain of Cu I with alternate Au I /bis(imidazolate) bridging scaffolds and strong unsupported Cu I –Cu I interactions has been generated, as well as a 28‐metal‐atoms cluster containing a nanopiece of Cu 2 O trapped by peripheral Au I /bis(imidazolate) moieties.

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