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Direct Conversion from Terminal Borylene into Terminal Phosphinidene
Author(s) -
Braunschweig Holger,
JimenezHalla J. Oscar C.,
Radacki Krzysztof,
Shang Rong
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201603548
Subject(s) - phosphinidene , terminal (telecommunication) , chemistry , mechanism (biology) , photochemistry , stereochemistry , computer science , physics , computer network , quantum mechanics
The first terminal manganese phosphinidene complex was quantitatively synthesized from a terminal alkylborylene complex. Its structure and bonding, as well as the reaction mechanism, were investigated through a combination of experimental and computational studies.