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Inside Back Cover: Triply Linked Corrole Dimers (Angew. Chem. Int. Ed. 22/2016)
Author(s) -
Ooi Shota,
Tanaka Takayuki,
Park Kyu Hyung,
Kim Dongho,
Osuka Atsuhiro
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201603127
Subject(s) - corrole , dimer , ring (chemistry) , cover (algebra) , crystallography , chemistry , stereochemistry , photochemistry , organic chemistry , mechanical engineering , engineering
Corrole, a ring‐contracted porphyrinoid with a trapezoid ("mountain‐like”) molecular shape, was successfully fused to the triply linked dimer by A. Osuka, D. Kim, T. Tanaka, and co‐workers in their Communication on page 6535 ff. This corrole was shown to be a closed‐shell non‐aromatic compound, whereas its reduction with NaBH 4 furnished the corresponding aromatic 3 H ‐corrole.