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Singlet Oxygen Formation during the Charging Process of an Aprotic Lithium–Oxygen Battery
Author(s) -
Wandt Johannes,
Jakes Peter,
Granwehr Josef,
Gasteiger Hubert A.,
Eichel RüdigerA.
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201602142
Subject(s) - singlet oxygen , oxygen , lithium (medication) , photochemistry , chemistry , electrolyte , singlet state , battery (electricity) , excited state , atomic physics , electrode , organic chemistry , medicine , power (physics) , physics , quantum mechanics , endocrinology
Aprotic lithium–oxygen (Li–O 2 ) batteries have attracted considerable attention in recent years owing to their outstanding theoretical energy density. A major challenge is their poor reversibility caused by degradation reactions, which mainly occur during battery charge and are still poorly understood. Herein, we show that singlet oxygen ( 1 Δ g ) is formed upon Li 2 O 2 oxidation at potentials above 3.5 V. Singlet oxygen was detected through a reaction with a spin trap to form a stable radical that was observed by time‐ and voltage‐resolved in operando EPR spectroscopy in a purpose‐built spectroelectrochemical cell. According to our estimate, a lower limit of approximately 0.5 % of the evolved oxygen is singlet oxygen. The occurrence of highly reactive singlet oxygen might be the long‐overlooked missing link in the understanding of the electrolyte degradation and carbon corrosion reactions that occur during the charging of Li–O 2 cells.