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Designed Assembly of Heterometallic Cluster Organic Frameworks Based on Anderson‐Type Polyoxometalate Clusters
Author(s) -
Li XinXiong,
Wang YangXin,
Wang RuiHu,
Cui CaiYan,
Tian ChongBin,
Yang GuoYu
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201602087
Subject(s) - polyoxometalate , diamondoid , cluster (spacecraft) , crystallography , iodide , type (biology) , chemistry , ligand (biochemistry) , materials science , inorganic chemistry , molecule , organic chemistry , catalysis , computer science , ecology , biochemistry , receptor , biology , programming language
A new approach to prepare heterometallic cluster organic frameworks has been developed. The method was employed to link Anderson‐type polyoxometalate (POM) clusters and transition‐metal clusters by using a designed rigid tris(alkoxo) ligand containing a pyridyl group to form a three‐fold interpenetrated anionic diamondoid structure and a 2D anionic layer, respectively. This technique facilitates the integration of the unique inherent properties of Anderson‐type POM clusters and cuprous iodide clusters into one cluster organic framework.