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Palladium(IV) in an Oxoanionic Environment: The XeF 2 Assisted Synthesis of [Pd(S 2 O 7 ) 3 ] 2−
Author(s) -
Bruns Jörn,
van Gerven David,
Klüner Thorsten,
Wickleder Mathias S.
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201601767
Subject(s) - palladium , chemistry , metal , atom (system on chip) , chelation , inorganic chemistry , medicinal chemistry , catalysis , organic chemistry , embedded system , computer science
For the first time tetravalent palladium is detected, coordinated exclusively by simple oxoanions. Stabilization was achieved by formation of the [Pd(S 2 O 7 ) 3 ] 2− complex in which three chelating disulfate groups surround the metal atom. The salt K 2 [Pd(S 2 O 7 ) 3 ] could only be obtained if the reaction of K 2 [PdCl 6 ] and neat SO 3 was performed in the presence of XeF 2 .
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