Cover Picture: Nucleophilic Reactivity of a Nitride‐Bridged Diuranium(IV) Complex: CO 2  and CS 2  Functionalization (Angew. Chem. Int. Ed. 12/2016) | Zendy

Falcone Marta | Zendy; Chatelain Lucile | Zendy; Mazzanti Marinella | Zendy

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Cover Picture: Nucleophilic Reactivity of a Nitride‐Bridged Diuranium(IV) Complex: CO 2 and CS 2 Functionalization (Angew. Chem. Int. Ed. 12/2016)

Author(s) -

Falcone Marta,

Chatelain Lucile,

Mazzanti Marinella

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201601759

Subject(s) - surface modification , cover (algebra) , int , reactivity (psychology) , nucleophile , nitride , chemistry , materials science , nanotechnology , layer (electronics) , computer science , organic chemistry , engineering , catalysis , operating system , mechanical engineering , medicine , alternative medicine , pathology

The Venus flytrap … … is used to illustrate the importance of a framework built from siloxide ligands and a Cs + ion in capturing abundant CO 2 and toxic CS 2 under ambient conditions and in promoting their reactions with a bridging nitride in a diuranium(IV) complex. In their Communication on page 4074 ff., M. Mazzanti et al. show how these processes lead to N−C bond formation and afford cyanate, thiocyanate, and unprecedented dicarbamate products.

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