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Cover Picture: Nucleophilic Reactivity of a Nitride‐Bridged Diuranium(IV) Complex: CO 2 and CS 2 Functionalization (Angew. Chem. Int. Ed. 12/2016)
Author(s) -
Falcone Marta,
Chatelain Lucile,
Mazzanti Marinella
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201601759
Subject(s) - surface modification , cover (algebra) , int , reactivity (psychology) , nucleophile , nitride , chemistry , materials science , nanotechnology , layer (electronics) , computer science , organic chemistry , engineering , catalysis , operating system , mechanical engineering , medicine , alternative medicine , pathology
The Venus flytrap … … is used to illustrate the importance of a framework built from siloxide ligands and a Cs + ion in capturing abundant CO 2 and toxic CS 2 under ambient conditions and in promoting their reactions with a bridging nitride in a diuranium(IV) complex. In their Communication on page 4074 ff., M. Mazzanti et al. show how these processes lead to N−C bond formation and afford cyanate, thiocyanate, and unprecedented dicarbamate products.