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Manganese(I)‐Catalyzed Substitutive C−H Allylation
Author(s) -
Liu Weiping,
Richter Sven C.,
Zhang Yujiao,
Ackermann Lutz
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201601560
Subject(s) - manganese , catalysis , chemistry , selectivity , carboxylate , scope (computer science) , combinatorial chemistry , diversification (marketing strategy) , stereochemistry , medicinal chemistry , organic chemistry , computer science , business , programming language , marketing
The first manganese(I)‐catalyzed C−H allylations with ample scope were achieved by carboxylate assistance. The highly selective C−H/C−O functionalizations proved viable with densely substituted allyl carbonates, and the organometallic C−H allylation strategy set the stage for expedient late‐stage diversification with excellent levels of positional selectivity.