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The Preparation of Complexes of Germanone from a Germanium μ‐Oxo Dimer
Author(s) -
Sinhababu Soumen,
Yadav Dhirendra,
Karwasara Surendar,
Sharma Mahendra Kumar,
Mukherjee Goutam,
Rajaraman Gopalan,
Nagendran Selvarajan
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201601445
Subject(s) - germanium , dimer , germanium compounds , formal synthesis , chemistry , materials science , stereochemistry , crystallography , organic chemistry , silicon
Complexes of germanone containing formal Ge=O→M bonds (M=Zn, B, Ge, Sn) were isolated and characterized. The compounds were prepared through a novel synthetic route using a germanium μ‐oxo dimer 3 as the starting material. This method circumvents the need to employ germanones to prepare complexes of germanones.