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Frontispiece: Distinct Mechanistic Differences in the Hydrogen‐Atom Transfer from Methane and Water by the Heteronuclear Oxide Cluster [Ga 2 MgO 4 ] .+
Author(s) -
Li Jilai,
Wu XiaoNan,
Zhou Shaodong,
Tang Shiya,
Schlangen Maria,
Schwarz Helmut
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201584261
Subject(s) - heteronuclear molecule , methane , oxide , cluster (spacecraft) , hydrogen , chemistry , hydrogen atom , phase (matter) , atom (system on chip) , chemical physics , crystallography , molecule , group (periodic table) , organic chemistry , computer science , programming language , embedded system
Mechanistic Differences In the gas phase, the heteronuclear oxide cluster [Ga 2 MgO 4 ] . reacts faster with water than with methane. In their Communication on page 12298 ff., H. Schwarz et al. explain this observation with different mechanisms of the two reactions.