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Frontispiece: Synthesis of an [(NHC) 2 Pd(SiMe 3 ) 2 ] Complex and Catalytic cis ‐Bis(silyl)ations of Alkynes with Unactivated Disilanes
Author(s) -
Ansell Melvyn B.,
Roberts Debbie E.,
Cloke F. Geoffrey N.,
Navarro Oscar,
Spencer John
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201581961
Subject(s) - silylation , catalysis , chemistry , cleavage (geology) , oxidative cleavage , oxidative phosphorylation , medicinal chemistry , stereochemistry , organic chemistry , materials science , biochemistry , fracture (geology) , composite material
cis‐Disilylations In their Communication on page 5578 ff., O. Navarro, J. Spencer et al. present the oxidative cleavage of Me 3 SiSiMe 3 . This reaction generates a precatalyst for the cis ‐disilylation of internal alkynes with nonactivated disilanes.