Frontispiece: Synthesis of an [(NHC) 2 Pd(SiMe 3 ) 2 ] Complex and Catalytic  cis ‐Bis(silyl)ations of Alkynes with Unactivated Disilanes | Zendy

Ansell Melvyn B. | Zendy; Roberts Debbie E. | Zendy; Cloke F. Geoffrey N. | Zendy; Navarro Oscar | Zendy; Spencer John | Zendy

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Frontispiece: Synthesis of an [(NHC) 2 Pd(SiMe 3 ) 2 ] Complex and Catalytic cis ‐Bis(silyl)ations of Alkynes with Unactivated Disilanes

Author(s) -

Ansell Melvyn B.,

Roberts Debbie E.,

Cloke F. Geoffrey N.,

Navarro Oscar,

Spencer John

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201581961

Subject(s) - silylation , catalysis , chemistry , cleavage (geology) , oxidative cleavage , oxidative phosphorylation , medicinal chemistry , stereochemistry , organic chemistry , materials science , biochemistry , fracture (geology) , composite material

cis‐Disilylations In their Communication on page 5578 ff., O. Navarro, J. Spencer et al. present the oxidative cleavage of Me 3 SiSiMe 3 . This reaction generates a precatalyst for the cis ‐disilylation of internal alkynes with nonactivated disilanes.

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