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Surface Coordination of Black Phosphorus for Robust Air and Water Stability
Author(s) -
Zhao Yuetao,
Wang Huaiyu,
Huang Hao,
Xiao Quanlan,
Xu Yanhua,
Guo Zhinan,
Xie Hanhan,
Shao Jundong,
Sun Zhengbo,
Han Weijia,
Yu XueFeng,
Li Penghui,
Chu Paul K.
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201512038
Subject(s) - black phosphorus , dispersion (optics) , phosphorus , ligand (biochemistry) , sulfonate , degradation (telecommunications) , titanium , inorganic chemistry , materials science , surface water , chemical engineering , chemistry , environmental chemistry , metallurgy , environmental engineering , environmental science , optics , computer science , physics , optoelectronics , telecommunications , biochemistry , sodium , receptor , engineering
Abstract A titanium sulfonate ligand is synthesized for surface coordination of black phosphorus (BP). In contrast to serious degradation observed from the bare BP, the BP after surface coordination exhibits excellent stability during dispersion in water and exposure to air for a long period of time, thereby significantly extending the lifetime and spurring broader application of BP.