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Molecularly Defined Nanostructures Based on a Novel AAA–DDD Triple Hydrogen‐Bonding Motif
Author(s) -
Papmeyer Marcus,
Vuilleumier Clément A.,
Pavan Giovanni M.,
Zhurov Konstantin O.,
Severin Kay
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201510423
Subject(s) - hydrogen bond , supramolecular chemistry , chemistry , crystallography , materials science , stereochemistry , nanotechnology , combinatorial chemistry , molecule , crystal structure , organic chemistry
A facile and flexible method for the synthesis of a new AAA–DDD triple hydrogen‐bonding motif is described. Polytopic supramolecular building blocks with precisely oriented AAA and DDD groups are thus accessible in few steps. These building blocks were used for the assembly of large macrocycles featuring four AAA–DDD interactions and a macrobicyclic complex with a total of six AAA–DDD interactions.