Quantifying the Electrocatalytic Turnover of Vitamin B 12 ‐Mediated Dehalogenation on Single Soft Nanoparticles | Zendy

Cheng Wei | Zendy; Compton Richard G. | Zendy

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Quantifying the Electrocatalytic Turnover of Vitamin B 12 ‐Mediated Dehalogenation on Single Soft Nanoparticles

Author(s) -

Cheng Wei,

Compton Richard G.

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201510394

Subject(s) - halogenation , nanoparticle , catalysis , turnover number , chemistry , trichloroethylene , vitamin , redox , vitamin b , vitamin d and neurology , inorganic chemistry , chemical engineering , materials science , nanotechnology , organic chemistry , biochemistry , endocrinology , medicine , engineering

We report the electrocatalytic dehalogenation of trichloroethylene (TCE) by single soft nanoparticles in the form of Vitamin B 12 ‐containing droplets. We quantify the turnover number of the catalytic reaction at the single soft nanoparticle level. The kinetic data shows that the binding of TCE with the electro‐reduced vitamin in the Co I oxidation state is chemically reversible.

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