A Bis(Diphosphanyl N‐Heterocyclic Carbene) Gold Complex: A Synthon for Luminescent Rigid AuAg 2  Arrays and Au 5  and Cu 6  Double Arrays | Zendy

Ai Pengfei | Zendy; Mauro Matteo | Zendy; De Cola Luisa | Zendy; Danopoulos Andreas A. | Zendy; Braunstein Pierre | Zendy

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A Bis(Diphosphanyl N‐Heterocyclic Carbene) Gold Complex: A Synthon for Luminescent Rigid AuAg 2 Arrays and Au 5 and Cu 6 Double Arrays

Author(s) -

Ai Pengfei,

Mauro Matteo,

De Cola Luisa,

Danopoulos Andreas A.,

Braunstein Pierre

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201510150

Subject(s) - synthon , carbene , luminescence , materials science , combinatorial chemistry , chemistry , stereochemistry , crystallography , optoelectronics , organic chemistry , catalysis

A mononuclear bis(NHC)/Au I (NHC=N‐heterocyclic carbene) cationic complex with a rigid bis(phosphane)‐functionalized NHC ligand (PC NHC P) was used to construct linear Au 3 and Ag 2 Au arrays, a Au 5 cluster with two intersecting crosslike Au 3 arrays, and an unprecedented Cu 6 complex with two parallel Cu 3 arrays. The impact of metallophilic interactions on photoluminescence was studied experimentally.

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