Back Cover: Alkali‐Metal‐Mediated Magnesiations of an N‐Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule (Angew. Chem. Int. Ed. 47/2015) | Zendy

MartínezMartínez Antonio J. | Zendy; Fuentes M. Ángeles | Zendy; HernánGómez Alberto | Zendy; Hevia Eva | Zendy; Kennedy Alan R. | Zendy; Mulvey Robert E. | Zendy; O'Hara Charles T. | Zendy

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Back Cover: Alkali‐Metal‐Mediated Magnesiations of an N‐Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule (Angew. Chem. Int. Ed. 47/2015)

Author(s) -

MartínezMartínez Antonio J.,

Fuentes M. Ángeles,

HernánGómez Alberto,

Hevia Eva,

Kennedy Alan R.,

Mulvey Robert E.,

O'Hara Charles T.

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201509531

Subject(s) - carbene , metalation , chemistry , stereochemistry , reactivity (psychology) , molecule , ligand (biochemistry) , metal , crystallography , receptor , organic chemistry , catalysis , medicine , biochemistry , alternative medicine , pathology

Extra! Extra! Read all about it! Para(normal) metalation of a pendant arene present on an N‐heterocyclic carbene has been observed. In their Communication on page 14075 ff., R. E. Mulvey et al. show that reaction of the NHC with a pre‐inverse‐crown template base induces three metal–ligand contacts: a normal NaC dative bond, an abnormal NaC bond, and a “paranormal” MgC bond at the para position of the pendant arene.

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