Dative Bonding between Group 13 Elements Using a Boron‐Centered Lewis Base | Zendy

Braunschweig Holger | Zendy; Dewhurst Rian D. | Zendy; Pentecost Leanne | Zendy; Radacki Krzysztof | Zendy; Vargas Alfredo | Zendy; Ye Qing | Zendy

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Dative Bonding between Group 13 Elements Using a Boron‐Centered Lewis Base

Author(s) -

Braunschweig Holger,

Dewhurst Rian D.,

Pentecost Leanne,

Radacki Krzysztof,

Vargas Alfredo,

Ye Qing

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201509289

Subject(s) - boron , dative case , group (periodic table) , base (topology) , frustrated lewis pair , lewis acids and bases , crystallography , chemistry , mathematics , linguistics , philosophy , organic chemistry , mathematical analysis , catalysis

An electron‐rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 Lewis acids using both its boron and nitrogen sites. The hard Lewis acid AlCl 3 binds through a nitrogen atom of the Lewis base, while softer Lewis acids GaX 3 (Cl, Br, I) bind at the boron atom. The latter are the first noncluster Lewis adducts between a boron‐centered Lewis base and a main‐group Lewis acid.

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