Visible‐Light‐Induced Hydrodifluoromethylation of Alkenes with a Bromodifluoromethylphosphonium Bromide | Zendy

Lin QingYu | Zendy; Xu XiuHua | Zendy; Zhang Ke | Zendy; Qing FengLing | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Visible‐Light‐Induced Hydrodifluoromethylation of Alkenes with a Bromodifluoromethylphosphonium Bromide

Author(s) -

Lin QingYu,

Xu XiuHua,

Zhang Ke,

Qing FengLing

Publication year - 2016

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201509282

Subject(s) - visible spectrum , bromide , photochemistry , chemistry , materials science , organic chemistry , optoelectronics

Bromodifluoromethylphosphonium bromide was solely used as the precursor of difluorocarbene. Herein, an unprecedented visible‐light‐induced hydrodifluoromethylation of alkenes with bromodifluoromethylphosphonium bromide using H 2 O and THF as hydrogen sources for the synthesis of difluoromethylated alkanes is described. This difluoromethylation is characterized by mild reaction conditions, ready availability of reagents, and excellent functional‐group tolerance.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research