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Well‐Defined, Mononuclear Bi I and Bi II Compounds: Towards Transition‐Metal‐Like Behavior
Author(s) -
Lichtenberg Crispin
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201509234
Subject(s) - reactivity (psychology) , characterization (materials science) , oxide , catalysis , transition metal , chemistry , inorganic chemistry , nanotechnology , materials science , organic chemistry , medicine , alternative medicine , pathology
Mononuclear Bi I and Bi II compounds remained elusive for a long time, but recently, the isolation and characterization of such species were reported. They can be handled in solution at ambient temperature and show exceptional properties, which are expected to reveal new reactivity patterns, enabling the development of new catalytic processes. TEMPO=2,2,6,6‐tetramethyl‐1‐piperidinyl N ‐oxide.