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Two‐Dimensional Nanoporous Networks Formed by Liquid‐to‐Solid Transfer of Hydrogen‐Bonded Macrocycles Built from DNA Bases
Author(s) -
Bilbao Nerea,
Destoop Iris,
De Feyter Steven,
GonzálezRodríguez David
Publication year - 2016
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201509233
Subject(s) - nanoporous , supramolecular chemistry , dna , materials science , pairing , base pair , base (topology) , hydrogen bond , nanotechnology , substrate (aquarium) , porosity , chemistry , molecule , organic chemistry , physics , mathematics , oceanography , geology , composite material , mathematical analysis , biochemistry , superconductivity , quantum mechanics
We present an approach that makes use of DNA base pairing to produce hydrogen‐bonded macrocycles whose supramolecular structure can be transferred from solution to a solid substrate. A hierarchical assembly process ultimately leads to two‐dimensional nanostructured porous networks that are able to host size‐complementary guests.