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Nanostructured Ni 2 P as a Robust Catalyst for the Hydrolytic Dehydrogenation of Ammonia–Borane
Author(s) -
Peng ChengYun,
Kang Lei,
Cao Shuang,
Chen Yong,
Lin ZheShuai,
Fu WenFu
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201508113
Subject(s) - ammonia borane , catalysis , dehydrogenation , bimetallic strip , hydrogen storage , activation energy , hydrogen , ammonia , hydrolysis , chemistry , hydrogen production , noble metal , inorganic chemistry , materials science , chemical engineering , organic chemistry , engineering
Ammonia–borane (AB) is a promising chemical hydrogen‐storage material. However, the development of real‐time, efficient, controllable, and safe methods for hydrogen release under mild conditions is a challenge in the large‐scale use of hydrogen as a long‐term solution for future energy security. A new class of low‐cost catalytic system is presented that uses nanostructured Ni 2 P as catalyst, which exhibits excellent catalytic activity and high sustainability toward hydrolysis of ammonia–borane with the initial turnover frequency of 40.4 mol (H2) mol (Ni2P) −1 min −1 under air atmosphere and at ambient temperature. This value is higher than those reported for noble‐metal‐free catalysts, and the obtained Arrhenius activation energy ( E a =44.6 kJ mol −1 ) for the hydrolysis reaction is comparable to Ru‐based bimetallic catalysts. A clearly mechanistic analysis of the hydrolytic reaction of AB based on experimental results and a density functional theory calculation is presented.