High‐Nuclearity Silver Thiolate Clusters Constructed with Phosphonates | Zendy

Xie YunPeng | Zendy; Jin JunLing | Zendy; Lu Xing | Zendy; Mak Thomas C. W. | Zendy

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High‐Nuclearity Silver Thiolate Clusters Constructed with Phosphonates

Author(s) -

Xie YunPeng,

Jin JunLing,

Lu Xing,

Mak Thomas C. W.

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201507512

Subject(s) - cluster (spacecraft) , phosphonate , crystallography , chemistry , ligand (biochemistry) , metal , stereochemistry , organic chemistry , biochemistry , receptor , computer science , programming language

The n ‐butylphosphonate ligand has been employed to construct three new silver(I) thiolate compounds. Single‐crystal X‐ray analysis revealed that complexes 1 and 2 are Ag 48 and Ag 51 coordination chain polymers, while 3 contains a discrete Ag 48 cluster, in which three different kinds of silver(I) thiolate cluster shells enclose three different phosphonate‐functionalized silver(I) cluster cores, respectively. The structures of clusters in 1 – 3 feature three three‐shell arrangements, S@Ag 12 @( n BuPO 3 ) 9 @Ag 36 S 23 , S@Ag 11 @( n BuPO 3 ) 7 (MoO 4 ) 2 @Ag 40 S 27 and MoO 4 @Ag 12 @( n BuPO 3 ) 8 S 6 @Ag 36 S 24 , respectively.

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