Visible‐Light‐Catalyzed Direct Benzylic C(sp 3 )–H Amination Reaction by Cross‐Dehydrogenative Coupling | Zendy

Pandey Ganesh | Zendy; Laha Ramkrishna | Zendy

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Visible‐Light‐Catalyzed Direct Benzylic C(sp 3 )–H Amination Reaction by Cross‐Dehydrogenative Coupling

Author(s) -

Pandey Ganesh,

Laha Ramkrishna

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201506990

Subject(s) - amination , catalysis , visible spectrum , chemistry , photochemistry , photoredox catalysis , amide , coupling reaction , combinatorial chemistry , photocatalysis , organic chemistry , materials science , optoelectronics

A conceptually new and synthetically valuable cross‐dehydrogenative benzylic C(sp 3 )–H amination reaction is reported by visible‐light photoredox catalysis. This protocol employs DCA (9,10‐dicyanoanthracene) as a visible‐light‐absorbing photoredox catalyst and an amide as the nitrogen source without the need of either a transition metal or an external oxidant.

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