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Synthesis, Single‐Crystal Structure and Characterization of (CH 3 NH 3 ) 2 Pb(SCN) 2 I 2
Author(s) -
Daub Michael,
Hillebrecht Harald
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201506449
Subject(s) - perovskite (structure) , characterization (materials science) , crystallography , crystal structure , single crystal , chemistry , crystal (programming language) , materials science , nanotechnology , computer science , programming language
The perovskite phase (CH 3 NH 3 ) 2 Pb(SCN) 2 I 2 with a structure closely related to the K 2 NiF 4 ‐type was identified as the product of the reaction of CH 3 NH 3 I and Pb(SCN) 2 by single‐crystal X‐ray analysis. This extends the range of suitable dyes for solar cell applications to a class of perovskite‐related structures of the general composition (AMX 3 ) n (AX) m .