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Rhodium‐Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane
Author(s) -
Morimoto Masao,
Miura Tomoya,
Murakami Masahiro
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201506328
Subject(s) - borylation , rhodium , catalysis , chemistry , terminal (telecommunication) , medicinal chemistry , organic chemistry , computer science , alkyl , aryl , telecommunications
Aliphatic terminal alkenes react with pinacolborane at ambient temperature to afford dehydrogenative borylation compounds as the major product when i Pr‐Foxap is used as the ligand with cationic rhodium(I) in the presence of norbornene, which acts as the sacrificial hydrogen acceptor. The reaction is applied to the one‐pot syntheses of aldehydes and homoallylic alcohols from aliphatic terminal alkenes.