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Accessing an Aromatic Diphosphatriazolate Anion by Formal Inorganic “Click” Chemistry
Author(s) -
HeringJunghans Christian,
Rivard Eric
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201505715
Subject(s) - cycloaddition , click chemistry , aromaticity , azide , chemistry , ion , block (permutation group theory) , combinatorial chemistry , molecule , organic chemistry , catalysis , mathematics , geometry
High five : A formal cycloaddition reaction between a chemical source of P 2 and azide (N 3 ) − affords the novel [P 2 N 3 ] − ion. Experimental and computational investigations confirm the presence of substantial aromaticity within this exciting new building block in inorganic chemistry.