Inside Back Cover: Short and Divergent Total Synthesis of (+)‐Machaeriol B, (+)‐Machaeriol D, (+)‐Δ 8 ‐THC, and Analogues (Angew. Chem. Int. Ed. 29/2015) | Zendy

Klotter Felix | Zendy; Studer Armido | Zendy

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Inside Back Cover: Short and Divergent Total Synthesis of (+)‐Machaeriol B, (+)‐Machaeriol D, (+)‐Δ 8 ‐THC, and Analogues (Angew. Chem. Int. Ed. 29/2015)

Author(s) -

Klotter Felix,

Studer Armido

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201505496

Subject(s) - stereoselectivity , stereospecificity , hydroboration , cover (algebra) , chemistry , stereochemistry , total synthesis , palladium , int , sequence (biology) , combinatorial chemistry , catalysis , organic chemistry , mechanical engineering , biochemistry , computer science , engineering , operating system

Machaeriols and cannabinoids can be synthesized by a short and divergent approach featuring highly efficient stereoselective transformations from a common precursor, commercially available ( S )‐perillic acid. In their Communication on page 8547 ff., A. Studer and F. Klotter report the use of a stereospecific palladium‐catalyzed decarboxylative γ‐arylation and a one‐pot sequence comprising a stereoselective hydroboration followed by oxidation or reduction as key steps.

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