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Rh III ‐Catalyzed CH Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal‐Ion Detection
Author(s) -
Kim Ju Hyun,
Gensch Tobias,
Zhao Dongbing,
Stegemann Linda,
Strassert Cristian A.,
Glorius Frank
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201504757
Subject(s) - catalysis , fluorescence , carbene , ion , chemistry , metal , metal ions in aqueous solution , photochemistry , organic chemistry , physics , quantum mechanics
The first CH bond activation with pyridotriazoles as coupling partners is presented using a Rh III catalyst. The pyridotriazoles can be used as new carbene precursors in CH activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metal ions.