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Insights into the Mechanism of Carbon Monoxide Dehydrogenase at Atomic Resolution
Author(s) -
Ribbe Markus W.
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201503979
Subject(s) - carbon monoxide dehydrogenase , carbon monoxide , nickel , chemistry , mechanism (biology) , resolution (logic) , photochemistry , catalysis , organic chemistry , physics , computer science , quantum mechanics , artificial intelligence
Unexpected similarities : Atomic‐resolution structures of CO 2 ‐ and NCO − ‐bound nickel‐containing carbon monoxide dehydrogenases (Ni‐CODHs) reveal that the reaction pathway of this enzyme involves an intermediate that is generated by two‐electron reduction.