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[Fe 19 ] “Super‐Lindqvist” Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe 2 (O t Bu) 6 ] with Ethanol
Author(s) -
Nachtigall Olaf,
Kusserow Matthias,
Clérac Rodolphe,
Wernsdorfer Wolfgang,
Menzel Michael,
Renz Franz,
Mrozinski Jerzy,
Spandl Johann
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201503647
Subject(s) - octahedron , ion , valence (chemistry) , crystallography , polymer , metal , metal ions in aqueous solution , crystal structure , coordination polymer , salt (chemistry) , materials science , chemistry , inorganic chemistry , polymer chemistry , organic chemistry
The syntheses, crystal structures, and physical properties of [HFe 19 O 14 (OEt) 30 ] and {Fe 11 (OEt) 24 } ∞ are reported. [HFe 19 O 14 (OEt) 30 ] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ 6 ‐oxo ligands is arranged in the rock salt structure. {Fe 11 (OEt) 24 } ∞ is a mixed‐valence coordination polymer in which Fe III metal ions form three 3D interpenetrating (10,3)‐b nets. The arrangement of the Fe III ions can also be compared to that of Si ions in α‐ThSi 2 . Thus, the described structures are at the interface between molecular and solid‐state chemistry.