Ethynyl Benziodoxolone (EBX): Installing Alkynes the Reversed Way | Zendy

Kaschel Johannes | Zendy; Werz Daniel B. | Zendy

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Ethynyl Benziodoxolone (EBX): Installing Alkynes the Reversed Way

Author(s) -

Kaschel Johannes,

Werz Daniel B.

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201503405

Subject(s) - hypervalent molecule , umpolung , reagent , electrophile , chemistry , reactivity (psychology) , iodine , functional group , combinatorial chemistry , aside , organic chemistry , catalysis , nucleophile , philosophy , medicine , polymer , alternative medicine , pathology , linguistics

Umpolung of alkynes : The hypervalent iodine reagent EBX (ethynyl benziodoxolone) can be employed for the electrophilic introduction of alkynes. Aside from its unusual reactivity, mild reaction conditions and a high tolerance towards various functional groups are remarkable features of this stable reagent and its reactions.

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