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Ethynyl Benziodoxolone (EBX): Installing Alkynes the Reversed Way
Author(s) -
Kaschel Johannes,
Werz Daniel B.
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201503405
Subject(s) - hypervalent molecule , umpolung , reagent , electrophile , chemistry , reactivity (psychology) , iodine , functional group , combinatorial chemistry , aside , organic chemistry , catalysis , nucleophile , philosophy , medicine , polymer , alternative medicine , pathology , linguistics
Umpolung of alkynes : The hypervalent iodine reagent EBX (ethynyl benziodoxolone) can be employed for the electrophilic introduction of alkynes. Aside from its unusual reactivity, mild reaction conditions and a high tolerance towards various functional groups are remarkable features of this stable reagent and its reactions.