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CoOOH Nanosheets with High Mass Activity for Water Oxidation
Author(s) -
Huang Junheng,
Chen Junting,
Yao Tao,
He Jingfu,
Jiang Shan,
Sun Zhihu,
Liu Qinghua,
Cheng Weiren,
Hu Fengchun,
Jiang Yong,
Pan Zhiyun,
Wei Shiqiang
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201502836
Subject(s) - nanosheet , electrocatalyst , oxide , transition metal , electron transfer , materials science , chemical engineering , cobalt , inorganic chemistry , adsorption , metal , catalysis , cobalt oxide , chemistry , nanotechnology , electrochemistry , electrode , photochemistry , metallurgy , biochemistry , engineering
Endowing transition‐metal oxide electrocatalysts with high water oxidation activity is greatly desired for production of clean and sustainable chemical fuels. Here, we present an atomically thin cobalt oxyhydroxide (γ‐CoOOH) nanosheet as an efficient electrocatalyst for water oxidation. The 1.4 nm thick γ‐CoOOH nanosheet electrocatalyst can effectively oxidize water with extraordinarily large mass activities of 66.6 A g −1 , 20 times higher than that of γ‐CoOOH bulk and 2.4 times higher than that of the benchmarking IrO 2 electrocatalyst. Experimental characterizations and first‐principles calculations provide solid evidence to the half‐metallic nature of the as‐prepared nanosheets with local structure distortion of the surface CoO 6− x octahedron. This greatly enhances the electrophilicity of H 2 O and facilitates the interfacial electron transfer between Co ions and adsorbed ‐OOH species to form O 2 , resulting in the high electrocatalytic activity of layered CoOOH for water oxidation.