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Versatile Electrochemical CH Amination via Zincke Intermediates
Author(s) -
Waldvogel Siegfried R.,
Möhle Sabine
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201502638
Subject(s) - amination , electrochemistry , cationic polymerization , chemistry , pyridine , combinatorial chemistry , nitrogen , organic chemistry , catalysis , electrode
Simply by applying electricity , the amination reaction of a broad variety of arenes, heteroarenes, and benzylic substrates is achieved. Pyridine serves as the nitrogen source and the intermediate cationic species are well‐protected from over‐oxidation.