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Fluorine‐Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions
Author(s) -
VentSchmidt Thomas,
Brosi Felix,
Metzger Jens,
Schlöder Tobias,
Wang Xuefeng,
Andrews Lester,
Müller Carsten,
Beckers Helmut,
Riedel Sebastian
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201502624
Subject(s) - fluorine , chemistry , inorganic chemistry , organic chemistry
Polyfluoride anions have been investigated by matrix‐isolation spectroscopy and quantum‐chemical methods. For the first time the higher polyfluoride anion [F 5 ] − has been observed under cryogenic conditions in neon matrices at 850 cm −1 . In addition, a new band for the Cs + [F 3 ] − complex in neon is reported.