Nickel‐Catalyzed Cross‐Coupling Reactions of  o ‐Carboranyl with Aryl Iodides: Facile Synthesis of 1‐Aryl‐ o ‐Carboranes and 1,2‐Diaryl‐ o ‐Carboranes | Zendy

Tang Cen | Zendy; Xie Zuowei | Zendy

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Nickel‐Catalyzed Cross‐Coupling Reactions of o ‐Carboranyl with Aryl Iodides: Facile Synthesis of 1‐Aryl‐ o ‐Carboranes and 1,2‐Diaryl‐ o ‐Carboranes

Author(s) -

Tang Cen,

Xie Zuowei

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201502502

Subject(s) - aryl , chemistry , nickel , catalysis , carborane , coupling reaction , transition metal , metal , medicinal chemistry , combinatorial chemistry , organic chemistry , alkyl

A nickel‐catalyzed arylation at the carbon center of o ‐carborane cages has been developed, thus leading to the preparation of a series of 1‐aryl‐ o ‐carboranes and 1,2‐diaryl‐ o ‐carboranes in high yields upon isolation. This method represents the first example of transition metal catalyzed C,C′‐diarylation by cross‐coupling reactions of o ‐carboranyl with aryl iodides.

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