Inside Back Cover: Developing Conjugated Polymers with High Electron Affinity by Replacing a CC Unit with a B ← N Unit (Angew. Chem. Int. Ed. 12/2015) | Zendy

Dou Chuandong | Zendy; Ding Zicheng | Zendy; Zhang Zijian | Zendy; Xie Zhiyuan | Zendy; Liu Jun | Zendy; Wang Lixiang | Zendy

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Inside Back Cover: Developing Conjugated Polymers with High Electron Affinity by Replacing a CC Unit with a B ← N Unit (Angew. Chem. Int. Ed. 12/2015)

Author(s) -

Dou Chuandong,

Ding Zicheng,

Zhang Zijian,

Xie Zhiyuan,

Liu Jun,

Wang Lixiang

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201501768

Subject(s) - homo/lumo , conjugated system , unit (ring theory) , polymer , electron affinity (data page) , electron , cover (algebra) , materials science , chemistry , electron transport chain , crystallography , physics , organic chemistry , molecule , mathematics , engineering , mechanical engineering , biochemistry , mathematics education , quantum mechanics

Far fewer n‐type polymer materials (low‐lying LUMO and HOMO; electron acceptors) than p‐type polymer materials (high‐lying LUMO and HOMO; electron donors) have been reported to date. In their Communication on page 3648 ff., J. Liu and co‐workers describe a strategy for the transformation of conjugated polymers from electron donors to electron acceptors. Their approach involves replacement of a CC unit by a B←N unit to lower both the LUMO and HOMO by approximately 0.6 eV.

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