Back Cover: Cycloparaphenylene‐Based Ionic Donor–Acceptor Supramolecule: Isolation and Characterization of Li + @C 60 ⊂[10]CPP (Angew. Chem. Int. Ed. 12/2015) | Zendy

Ueno Hiroshi | Zendy; Nishihara Taishi | Zendy; Segawa Yasutomo | Zendy; Itami Kenichiro | Zendy

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Back Cover: Cycloparaphenylene‐Based Ionic Donor–Acceptor Supramolecule: Isolation and Characterization of Li + @C 60 ⊂[10]CPP (Angew. Chem. Int. Ed. 12/2015)

Author(s) -

Ueno Hiroshi,

Nishihara Taishi,

Segawa Yasutomo,

Itami Kenichiro

Publication year - 2015

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201501644

Subject(s) - delocalized electron , ionic bonding , supramolecular chemistry , cationic polymerization , acceptor , cover (algebra) , electrochemistry , fullerene , ring (chemistry) , charge (physics) , materials science , ion , crystallography , ionic liquid , characterization (materials science) , chemistry , nanotechnology , polymer chemistry , crystal structure , electrode , organic chemistry , physics , quantum mechanics , catalysis , mechanical engineering , engineering , condensed matter physics

A strong charge‐transfer interaction between [10]cycloparaphenylene (CPP) and Li + @C 60 in the first CPP‐based ionic donor–acceptor supramolecule Li + @C 60 ⊂[10]CPP⋅X − is confirmed by electrochemical measurement and spectroscopic analyses. K. Itami and co‐workers show in their Communication on page 3707 ff. that the cationic charge on the Li + ion is delocalized not only onto the fullerene cage, but also further onto the outer CPP ring. Thus the whole compound is a well‐structured, supramolecular cation.

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