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High‐Fidelity Noncovalent Synthesis of Hydrogen‐Bonded Macrocyclic Assemblies
Author(s) -
MontoroGarcía Carlos,
CamachoGarcía Jorge,
LópezPérez Ana M.,
Bilbao Nerea,
RomeroPérez Sonia,
Mayoral María J.,
GonzálezRodríguez David
Publication year - 2015
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201501321
Subject(s) - tetramer , monomer , hydrogen bond , non covalent interactions , hydrogen , chemistry , nanotechnology , materials science , combinatorial chemistry , polymer chemistry , computational chemistry , molecule , organic chemistry , polymer , enzyme
A hydrogen‐bonded cyclic tetramer is assembled with remarkably high effective molarities from a properly designed dinucleoside monomer. This self‐assembled species exhibits an impressive thermodynamic and kinetic stability and is formed with high fidelities within a broad concentration range.